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- W2950731237 abstract "The first total synthesis of (±)-methyl gummiferolate (1b) has been achieved with a high diastereoselectivity. The key steps included the homoallyl−homoallyl radical rearrangement reaction of the enyne 8 to afford the suitably functionalized bicyclo[2.2.2]octane 9 and the intramolecular Diels−Alder reaction of the tetraene 12 for the construction of the AB ring system of 1b." @default.
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- W2950731237 date "1999-10-15" @default.
- W2950731237 modified "2023-10-18" @default.
- W2950731237 title "First Total Synthesis of (±)-Methyl Gummiferolate Using a Homoallyl−Homoallyl Radical Rearrangement Reaction" @default.
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- W2950731237 doi "https://doi.org/10.1021/ol990264u" @default.
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