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• W2950732009 abstract "The electrical conductivity of the transition metal oxide Co1-σO has been measured as a function of the oxygen activity and the temperature in the whole stability field of CoO using a very pure single crystal. The results are modelled in terms of a new conductivity model in which free electron holes as well as electron holes which are trapped by cation vacancies contribute to the conductivity. At low oxygen activities also electrons are considered. Within this model the following parameters are obtained: the two mass action constants, K1 and K11, for the incorporation of oxygen and the formation of singly ionized vacancies, the mobilities of free and trapped electron holes, b0 and b1, and the product of the electron mobility and the electronic mass action constant, Kebe. A microscopic interpretation of the model is made possible by translating the so-called five-frequency model for impurity diffusion to the conductivity problem. Then it is also possible to estimate the lifetime of the associate consisting of a doubly ionized vacancy and an electron hole, which is about twenty times larger than the residence time of an electron hole on a cation site." @default.
• W2950732009 created "2019-06-27" @default.
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• W2950732009 date "1997-02-01" @default.
• W2950732009 modified "2023-10-18" @default.
• W2950732009 title "The electrical conductivity of CoO: Experimental results and a new conductivity model" @default.
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• W2950732009 doi "https://doi.org/10.1002/bbpc.19971010204" @default.
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