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- W2950733412 endingPage "228" @default.
- W2950733412 startingPage "214" @default.
- W2950733412 abstract "We have demonstrated that chemical efficiency of biocatalysts mediated reactions could be improved by several chemical methodologies. Herin, I report the results focus to three topics: (1)Design of building blocks for organic synthesis via yeast-mediated asymmetric reduction of ketones. (2)Synthesis of chiral gem-difluorocyclopropanes using lipase-catalyzed reaction and linker-oriented design of binaphthol derivatives for optical resolution using lipase-catalyzed reaction. (3)Innovation of lipase-catalyzed reactions by the use of ionic liquids solvent system. We have succeeded in showing that activation of lipase-performances has been accomplished by the coating of enzyme with alkyl PEG ionic liquid. Furthermore, a rational design of phosphonium ionic liquid for ionic liquid coated-lipase (IL1-PS)-catalyzed reaction has been investigated, and very rapid transesterification of secondary alcohols accomplished when IL1-PS was used as catalyst in 2-methoxyethoxymethyl(tri-n-butyl)phosphonium bis(trifluoromethanesulfonyl)amide ([P444MEM] [NTf2]) as solvent while perfect enantioselectivity was maintaining. Increased Kcat value was suggested to be the most important factor in IL1-PS working the best in [P444MEM] [NTf2] solvent." @default.
- W2950733412 created "2019-06-27" @default.
- W2950733412 creator A5029436502 @default.
- W2950733412 date "2011-01-01" @default.
- W2950733412 modified "2023-10-06" @default.
- W2950733412 title "Development of Environmental Benign Organic Synthesis based on Advanced Biocatalysis Processes Regulated by a Chemical Method" @default.
- W2950733412 cites W1932652454 @default.
- W2950733412 cites W1964020603 @default.
- W2950733412 cites W1966992826 @default.
- W2950733412 cites W1969729367 @default.
- W2950733412 cites W1972693631 @default.
- W2950733412 cites W1973869966 @default.
- W2950733412 cites W1976411897 @default.
- W2950733412 cites W1980442483 @default.
- W2950733412 cites W1980491171 @default.
- W2950733412 cites W1981560246 @default.
- W2950733412 cites W1984943393 @default.
- W2950733412 cites W1989199746 @default.
- W2950733412 cites W1990584423 @default.
- W2950733412 cites W1991483044 @default.
- W2950733412 cites W1992252389 @default.
- W2950733412 cites W1992480888 @default.
- W2950733412 cites W1994139775 @default.
- W2950733412 cites W1994478595 @default.
- W2950733412 cites W1995333376 @default.
- W2950733412 cites W1995544527 @default.
- W2950733412 cites W1996030297 @default.
- W2950733412 cites W1996900989 @default.
- W2950733412 cites W1998727387 @default.
- W2950733412 cites W1999110019 @default.
- W2950733412 cites W1999758085 @default.
- W2950733412 cites W2000525991 @default.
- W2950733412 cites W2000627657 @default.
- W2950733412 cites W2006261131 @default.
- W2950733412 cites W2007055921 @default.
- W2950733412 cites W2010367518 @default.
- W2950733412 cites W2010370307 @default.
- W2950733412 cites W2011241000 @default.
- W2950733412 cites W2011291216 @default.
- W2950733412 cites W2012336269 @default.
- W2950733412 cites W2012481176 @default.
- W2950733412 cites W2015852486 @default.
- W2950733412 cites W2017157005 @default.
- W2950733412 cites W2018912013 @default.
- W2950733412 cites W2022977892 @default.
- W2950733412 cites W2023527829 @default.
- W2950733412 cites W2025502800 @default.
- W2950733412 cites W2026479236 @default.
- W2950733412 cites W2026813683 @default.
- W2950733412 cites W2029533127 @default.
- W2950733412 cites W2030387220 @default.
- W2950733412 cites W2030776893 @default.
- W2950733412 cites W2033495093 @default.
- W2950733412 cites W2037839404 @default.
- W2950733412 cites W2037962604 @default.
- W2950733412 cites W2040160941 @default.
- W2950733412 cites W2043736770 @default.
- W2950733412 cites W2044233481 @default.
- W2950733412 cites W2044399364 @default.
- W2950733412 cites W2045467060 @default.
- W2950733412 cites W2045662932 @default.
- W2950733412 cites W2050409212 @default.
- W2950733412 cites W2050432173 @default.
- W2950733412 cites W2051464769 @default.
- W2950733412 cites W2051885226 @default.
- W2950733412 cites W2053041708 @default.
- W2950733412 cites W2054110266 @default.
- W2950733412 cites W2054111891 @default.
- W2950733412 cites W2054641247 @default.
- W2950733412 cites W2058710113 @default.
- W2950733412 cites W2060686603 @default.
- W2950733412 cites W2062031433 @default.
- W2950733412 cites W2066924235 @default.
- W2950733412 cites W2068527479 @default.
- W2950733412 cites W2069190367 @default.
- W2950733412 cites W2069638509 @default.
- W2950733412 cites W2070650017 @default.
- W2950733412 cites W2071754873 @default.
- W2950733412 cites W2074412644 @default.
- W2950733412 cites W2074926789 @default.
- W2950733412 cites W2076456838 @default.
- W2950733412 cites W2078833642 @default.
- W2950733412 cites W2086516923 @default.
- W2950733412 cites W2088668995 @default.
- W2950733412 cites W2090919141 @default.
- W2950733412 cites W2091229403 @default.
- W2950733412 cites W2092668272 @default.
- W2950733412 cites W2093546622 @default.
- W2950733412 cites W2095694732 @default.
- W2950733412 cites W2101454188 @default.
- W2950733412 cites W2106999995 @default.
- W2950733412 cites W2107719944 @default.
- W2950733412 cites W2111685942 @default.
- W2950733412 cites W2115862978 @default.
- W2950733412 cites W2122250145 @default.
- W2950733412 cites W2124985647 @default.
- W2950733412 cites W2136079838 @default.
- W2950733412 cites W2140466011 @default.