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- W2950737622 abstract "trans-Isohumulones, dihydroisohumulones, tetrahydroisohumulones, and humulinones, which are important hop-derived flavor components of beer, were found, by using electrolysis of organic solutions, to be stable against oxidation, like weak acids; however, they are readily oxidized in their anionic forms as present in beer. Oxygen- and carbon-centered radicals were formed by oxidation and identified by using spin trapping under aerobic and anaerobic conditions, followed by EPR (electron paramagnetic resonance) spectroscopy. Generated radicals were reactive, most likely degrading into products lacking the tricarbonyl chromophore; this is typical of five-membered-ring hop derivatives. Thus, flavor-active beer constituents may degrade oxidatively in the absence of oxygen, thereby leading to reaction products that escape UV detection." @default.
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- W2950737622 date "2004-01-13" @default.
- W2950737622 modified "2023-09-27" @default.
- W2950737622 title "Radicaloid-Type Oxidative Decomposition of Beer Bittering Agents Revealed." @default.
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- W2950737622 doi "https://doi.org/10.1002/chin.200402185" @default.
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