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- W2950757242 abstract "Abstract 1,2-H shift is the only intramolecular reaction of 7-(1-propenyloxy)-1-indanylidenes ( 8 ) whereas 7-(2-propenyloxy)-1-indanylidene ( 13 ) and 7-(2-butenyloxy)-1-indanylidenes ( 19 ) undergo addition to the side-chain CC bond and 1,2-H shifts competitively. Owing to the small RCR bond angle of 1-indanylidenes, the intramolecular chemistry is dominated by the singlet state even if the carbenes are generated by tripletsensitize photolysis ( k TS > K T )." @default.
- W2950757242 created "2019-06-27" @default.
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- W2950757242 date "2010-08-03" @default.
- W2950757242 modified "2023-09-26" @default.
- W2950757242 title "ChemInform Abstract: Intramolecular Reactivity of Functionalized Arylcarbenes: 7-Alkenyloxy- 1-indanylidenes." @default.
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- W2950757242 doi "https://doi.org/10.1002/chin.199723112" @default.
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