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- W2950757632 abstract "The chiral Pt catalyst precursor Pt((R,R)-Me-Duphos)(Ph)(Cl) mediated alkylation of racemic secondary phosphines PHR(R') with benzyl halides in the presence of base to give enantioenriched tertiary phosphines PR(R')(CH2Ar). Similar reactions of bis(secondary) phosphines yielded chiral diphosphines in up to 93% ee and with good rac/meso diastereoselection." @default.
- W2950757632 created "2019-06-27" @default.
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- W2950757632 date "2006-02-03" @default.
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- W2950757632 title "Platinum-Catalyzed Asymmetric Alkylation of Secondary Phosphines: Enantioselective Synthesis of P-Stereogenic Phosphines" @default.
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- W2950757632 doi "https://doi.org/10.1021/ja058096q" @default.
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