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- W2950771423 abstract "The total synthesis of the indole alkaloid trinervine 1 was accomplished in enantiospecific fashion in an overall yield of 20% (from the tetracyclic ketone 8) in 10 reaction vessels (12.5% from tryptophan methyl ester). The synthesis of the Na-H substituted macroline equivalent 2 was also completed in high yield via the same intermediate 13. The unique protection/hydroboration process developed here should provide a method to functionalize the C(19)−C(20) double bond in similar systems." @default.
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- W2950771423 date "2001-11-16" @default.
- W2950771423 modified "2023-10-05" @default.
- W2950771423 title "General Approach for the Synthesis of Sarpagine/Macroline Indole Alkaloids. Enantiospecific Total Synthesis of the Indole Alkaloid Trinervine" @default.
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- W2950771423 doi "https://doi.org/10.1021/ol0101990" @default.
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