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- W2950778957 abstract "Dimethylsilanyl [Me2Si(H)] ketene S,O-acetal 6b is an effective nucleophile that retards the undesirable Si+-catalyzed racemic pathway in the oxazaborolidinone-catalyzed asymmetric Michael reaction. Through the further suppression of the Si+-catalyzed pathway by carrying out the reaction in the presence of 2,6-diisopropylphenol and t-BuOMe as additives, enantioselectivity up to 98% ee could be achieved for a variety of acyclic enones." @default.
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- W2950778957 date "2004-12-01" @default.
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- W2950778957 title "Dimethylsilyl Ketene Acetal as a Nucleophile in Asymmetric Michael Reaction: Enhanced Enantioselectivity in Oxazaborolidinone-Catalyzed Reaction" @default.
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- W2950778957 doi "https://doi.org/10.1021/ol048071g" @default.
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