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- W2950781612 abstract "Xanthates are convenient precursors of a variety of radicals that can be captured in an inter- or intramolecular fashion. Overall, the process involves rupture of the sulfide C-S bond and addition of the elements of the xanthate to the olefinic trap. The xanthate in the product can be used in another radical sequence or ionically modified in a great variety of ways. S-Propargyl xanthates exhibit a special but interesting behaviour which involves a sigmatropic rearrangement to the corresponding allene and ring closure to a novel betaine." @default.
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- W2950781612 date "1999-04-01" @default.
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- W2950781612 title "Some New Radical Reactions of Xanthates" @default.
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- W2950781612 doi "https://doi.org/10.1002/jccs.199900021" @default.
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