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- W2950791273 abstract "The synthesis of densly functionized α-silyl-β-hydroxyl vinylsilanes via ruthenium-catalyzed multicomponent reaction (MCR) is reported herein. Exceptionally high regio- and diastereoselectivity was achieved by employing an unprecedented hydrosilylation of bifunctional silyl-propargyl boronates. The simple protocol, mild reaction conditions, and unique tolerability of this method make it a valuable tool for the synthesis of highly elaborated building blocks. The one-pot synthesis of stereodefined olefins, the generation of a valuable cyclohexene building block through a four-component MCR, and further functionalization in an abundance of diastereoselective reactions is disclosed herein." @default.
- W2950791273 created "2019-06-27" @default.
- W2950791273 creator A5004004852 @default.
- W2950791273 creator A5032412691 @default.
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- W2950791273 date "2016-06-01" @default.
- W2950791273 modified "2023-09-27" @default.
- W2950791273 title "ChemInform Abstract: Ruthenium-Catalyzed Multicomponent Reactions: Access to α-Silyl-β-Hydroxy Vinylsilanes, Stereodefined 1,3-Dienes, and Cyclohexenes." @default.
- W2950791273 cites W2215140355 @default.
- W2950791273 doi "https://doi.org/10.1002/chin.201628067" @default.
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