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- W2950807601 abstract "Advances in catalytic methodology are limited by the available tools for systematically optimizing catalyst structure. For molecular transition-metal catalysts, this optimization process typically involves two principle parameters: the identity of the active metal center and the environment presented by supporting ligands. In this Account, we highlight our group’s efforts to exploit nuclearity as a parameter in catalyst design. We recently reported a binucleating naphthyridine–diimine (NDI) ligand that supports coordinatively unsaturated nickel–nickel bonds across a broad range of formal oxidation states. Taking advantage of ligand-centered redox activity, these dinickel complexes function as robust platforms for catalytic transformations, including hydrosilylation and alkyne cyclotrimerization reactions. Our results collectively demonstrate that nuclearity effects provide a complementary means of modulating the activity and selectivity of transition metal catalysts. 1 Introduction 2 Group 10 Metal–Metal Bonds in Catalysis 3 Dinuclear Nickel Complexes Supported by Redox-Active Ligands 4 Multielectron Redox Transformations at Metal–Metal Bonds 5 Dinuclear Silane Activation and Catalytic Hydrosilylations 6 Selective Alkyne Cyclotrimerization 7 Conclusions" @default.
- W2950807601 created "2019-06-27" @default.
- W2950807601 creator A5017874065 @default.
- W2950807601 creator A5036367572 @default.
- W2950807601 creator A5060118311 @default.
- W2950807601 date "2016-05-01" @default.
- W2950807601 modified "2023-09-27" @default.
- W2950807601 title "ChemInform Abstract: Catalytically Active Nickel-Nickel Bonds Using Redox-Active Ligands" @default.
- W2950807601 cites W2324062213 @default.
- W2950807601 doi "https://doi.org/10.1002/chin.201622247" @default.
- W2950807601 hasPublicationYear "2016" @default.
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