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- W2950809166 abstract "Abstract Prochiral dialkylacetal derivatives of 3-hydroxy-2-hydroxymethylpropanal 6a-e were synthesized from the corresponding 2-substituted diethyl malonates 5a-e and subjected to asymmetric enzymatic acetylation. The diethyl malonates 5a-f were prepared from diethyl chloromethylenemalonate 3 by using either a one- or a two-step process. Asymmetric acetylation of 3-hydroxy-2-hydroxymethylpropanal diethyl acetal 6b with several enzymes was studied first, showing the highest enantiotopic selectivity with lipase from Pseudomonas fluorescens (PfL). Solvent effect was also investigated: the best selectivity was obtained in a mixture of hexane and diethyl ether. Furthermore, several other acetals 6a-e were also tested under the optimal acetylation conditions." @default.
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- W2950809166 date "2010-08-03" @default.
- W2950809166 modified "2023-09-26" @default.
- W2950809166 title "ChemInform Abstract: Synthesis and Lipase-Catalyzed Asymmetric Acetylation of 3-Hydroxy-2- hydroxymethylpropanal Acetals." @default.
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- W2950809166 doi "https://doi.org/10.1002/chin.199727077" @default.
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