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- W2950810954 abstract "Abstract 1,3-dipolar cycloaddition of N-phenylmaleimide with azomethine ylides generated from α-aminonitrile or α-aminoester oxazolidines gave bicyclic imides, which were reduced regio- and stereoselectively to hydroxylactams. In the aminonitrile series, reduction with NaBH 4 /CeCl 3 at low temperature gave a single hydroxylactam in high yield. In the aminoester series the regioselectivity was more dependent on the structure, and other conditions (LiBEt 3 H) were found to obtain a single hydroxylactam which corresponds to a reverse regiochemistry when compared with the aminonitrile series." @default.
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- W2950810954 date "2010-08-20" @default.
- W2950810954 modified "2023-09-26" @default.
- W2950810954 title "ChemInform Abstract: Regio- and Stereoselective Reduction of Bicyclic Imides for the Asymmetric Synthesis of Highly Substituted Pyrrolidines." @default.
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- W2950810954 doi "https://doi.org/10.1002/chin.199336174" @default.
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