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- W2950814892 abstract "A synthesis of the insect toxin pederin (1) based upon the union of metallated dihydropyran 8 with the oxamate ester derivative 9 is described. Noteworthy features include (a) a new method for the construction of metallated dihydropyrans which tolerates heteroatom functionality and (b) a rhodium-catalyzed hydroboration reaction which enables stereocontrolled formation of the stereogenic centre at C10." @default.
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- W2950814892 date "1991-01-01" @default.
- W2950814892 modified "2023-10-14" @default.
- W2950814892 title "Pederin: The Metallated Dihydropyran Approach. Stereoselective Reduction of<i>N</i>-Acylimidates<i>via</i>Rhodium-Catalysed Hydroboration" @default.
- W2950814892 doi "https://doi.org/10.1055/s-1991-28418" @default.
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