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- W2950816259 abstract "A single acetonitrile exchange process on Co(diap)(MeCN)32+ (where diap is 2,2-di(aminomethyl)-propan-1-ol) in acetonitrile solution is observed by 14N N.M.R. between 221 and 315.6 K. On the assumption that this process characterizes the two equivalent acetonitrile sites the following parameters are derived: kex(298 K) = (45 ± 3) x 105 s-1, ΔH? = 3l.0 ± 2.5 kJ mol-1, ΔS? = -l4 ± 6 J Mol-1 K-1, where the exchange rate is given by 2kex[Co(diap)(MeCN)32+]. Alternative interpretations are also discussed." @default.
- W2950816259 created "2019-06-27" @default.
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- W2950816259 date "1974-07-23" @default.
- W2950816259 modified "2023-09-26" @default.
- W2950816259 title "ChemInform Abstract: THE MODIFICATION OF COORDINATED ACETONITRILE LABILITY ON COBALT(II) INDUCED BY THE COORDINATION OF 2,2-DI(AMINOMETHYL)PROPAN-1-OL" @default.
- W2950816259 cites W2318035074 @default.
- W2950816259 doi "https://doi.org/10.1002/chin.197429371" @default.
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