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- W2950822059 abstract "The [3, 3] sigmatropic rearrangement, represented by Claisen rearrangement, is one of the promising synthetic tools for the carbon framework construction in natural product synthesis. The reliability of the stereochemical issue, especially being realizable in cyclic systems, is well recognized. In this article, we summarize our recent development in the field of the Claisen rearrangements applied to the carbohydrate-derived substrates. The highly stereoselective quaternization of the ring-carbon of the furanose derivatives is also featured in this context. The utility of the rearrangement strategy was substantiated through the first total synthesis of (-) -acetomycin, an antimicrobial and antitumor agent." @default.
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- W2950822059 date "1991-01-01" @default.
- W2950822059 modified "2023-10-06" @default.
- W2950822059 title "The claisen rearrangement using carbohydrate-derived substrates and its application to total synthesis of (-)-acetomycin." @default.
- W2950822059 cites W2026106480 @default.
- W2950822059 doi "https://doi.org/10.5059/yukigoseikyokaishi.49.327" @default.
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