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- W2950824622 abstract "Abstract Boratabenzenes ( 4 ) are six π-electron aromatic anions which can serve as versatile ligands towards Zr(IV) and Zr(II). The reaction of 4 with ZrCl 4 affords bis(boratabenzene)zirconium(IV) dichlorides ( 11 ), which on treatment with BuLi and excess PMe 3 give bis(boratabenzene)bis(trimethylphosphine)zirconium(II) ( 27 ). On activation by excess methylaluminoxane 11 are the catalysts for the polymerization or oligomerization of ethylene. Bridged boratabenzene zirconium dichlorides 19 , 20 , and 21 , which closely resemble the corresponding ansa-zirconocenes, can be similarly activated for polymerization of ethylene. Compound 27 reacts with 1,3-diynes to afford zirconacycles 31 and with acetylene by ring annulation to afford 32 ." @default.
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- W2950824622 date "2010-06-13" @default.
- W2950824622 modified "2023-09-24" @default.
- W2950824622 title "ChemInform Abstract: Boratabenzenes: From Chemical Curiosities to Promising Catalysts" @default.
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- W2950824622 doi "https://doi.org/10.1002/chin.199935026" @default.
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