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- W2950825524 abstract "An efficient Negishi cross-coupling was developed for the synthesis of the biaryl axes present in useful P-chiral dihydrobenzooxaphosphole ligands. This approach has allowed for the synthesis of new derivatives of these ligands that were not accessible by the previous route employing Suzuki–Miyaura cross-coupling. The use of Pd2(dba)3/BI-DIME as the catalyst system affords the desired biaryl compounds in good yields with excellent rates and with catalyst loadings as low as 0.25 mol %." @default.
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- W2950825524 date "2016-05-01" @default.
- W2950825524 modified "2023-09-23" @default.
- W2950825524 title "ChemInform Abstract: Synthesis of P-Chiral Dihydrobenzooxaphospholes Through Negishi Cross-Coupling." @default.
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- W2950825524 doi "https://doi.org/10.1002/chin.201623064" @default.
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