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• W2950837306 abstract "A copper(I) complex with thiacalix[3]pyridine, [Cu(Py3S3)]2(PF6)2, is a competent catalyst for aziridination of olefins. The reaction of styrene (1 equiv) with PhI=NTs (1 equiv) at 20 °C produced N-(p-toluenesulfonyl)-2-phenylaziridine (71%, turnover number = 55) in the presence of 1.2 mol % catalyst under aerobic conditions. The turnover number increased up to 350 with a 0.12 mol % catalyst and a 5:1 styrene/PhI=NTs ratio in 41% yield." @default.
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• W2950837306 date "2008-04-05" @default.
• W2950837306 modified "2023-10-18" @default.
• W2950837306 title "A Thiacalix[3]pyridine Copper(I) Complex as a Highly Active Catalyst for the Olefin Aziridination Reaction" @default.
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• W2950837306 doi "https://doi.org/10.1246/cl.2008.452" @default.
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