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- W2950840483 abstract "The oxidative cyclization of the ethylidene derivative of 3-hydrazinoacenaphtho[1,2-e][1,2,4]triazine (2) gave regioselectively the angular isomer 1-methylacenaphtho[1,2-e][1,2,4]triazolo[3,4-c][1,2,4]triazine (5). Its linear isomer 10-methylacenaphtho[1,2-e][1,2,4]triazolo[4,3-b][1,2,4]triazine (4) was synthesized by the condensation of acenaphthenequinone (6) with 3,4-diamino-5-methyl-4H-1,2,4-triazole. Condensation of 2 with a number of monosaccharides afforded the respective hydrazones 9 whose oxidative cyclization gave the corresponding 1-(polyhydroxyalkyl)acenaphtho[1,2-e][1,2,4]triazolo[3,4-c][1,2,4]triazine (10). Acetylation of 9 and 10 gave 3-[N-acetyl-N′-(polyacetoxyalkylidene)hydrazino]acenaphtho[1,2-e][1,2,4]triazine (11) and 1-(polyacetoxyalkyl)acenaphtho[1,2-e][1,2,4]triazolo[3,4-c][1,2,4]triazine (13) respectively. Periodate oxidation of 9e gave 3-(2-oxoethylidenehydrazino)acenaphtho[1,2-e][1,2,4]triazine (14)." @default.
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- W2950840483 title "Regioisomeric Formation of Acenaphtho[1,2-<i>e</i>][1,2,4]triazolo[3,4-<i>c</i>][1,2,4]triazines and Their Acyclic C-Nucleoside Analogues" @default.
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- W2950840483 doi "https://doi.org/10.1246/bcsj.67.149" @default.
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