Matches in SemOpenAlex for { <https://semopenalex.org/work/W2950846650> ?p ?o ?g. }
Showing items 1 to 73 of
73
with 100 items per page.
- W2950846650 abstract "Treatment of dimethylhydroquinone dimethyl ethers (ortho and meta isomers) with glycopyranose pentaacetates (D-gluco, D-galacto) in the presence of SnCl4 and F3CCO2Ag selectively afforded the corresponding C-β-D-glycosyl derivatives by aromatic electrophilic substitution. Oxidation of the dimethoxybenzene moiety with ceric ammonium nitrate delivered C-β-D-glycosyl-dimethylbenzoquinones, which were reduced with Na2S2O4 to the corresponding C-β-D-glycosyl-dimethylhydroquinones. ZnCl2-catalyzed cyclization either with methylbut-2-en-1-ol (prenyl alcohol) or with all-racemic phytol led to acetyl-protected C-β-D-glycosyl chromanols or C-β-D-glycosyl tocopherols, the sugar residues of which were deacetylated under base catalysis conditions. These new molecules were evaluated as antioxidants in terms of their ability to inhibit the peroxidation of linoleic acid in SDS micelles. The position of the C-glucosyl moiety on the phenolic nucleus emerges as the critical structural determinant of their activity. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)" @default.
- W2950846650 created "2019-06-27" @default.
- W2950846650 creator A5001180898 @default.
- W2950846650 creator A5021324401 @default.
- W2950846650 creator A5024989470 @default.
- W2950846650 creator A5048198045 @default.
- W2950846650 creator A5057691408 @default.
- W2950846650 creator A5080574479 @default.
- W2950846650 creator A5090012953 @default.
- W2950846650 date "2008-07-22" @default.
- W2950846650 modified "2023-09-25" @default.
- W2950846650 title "ChemInform Abstract: C-D-Glucopyranosyl Derivatives of Tocopherols - Synthesis and Evaluation as Amphiphilic Antioxidants." @default.
- W2950846650 cites W2139117727 @default.
- W2950846650 doi "https://doi.org/10.1002/chin.200830077" @default.
- W2950846650 hasPublicationYear "2008" @default.
- W2950846650 type Work @default.
- W2950846650 sameAs 2950846650 @default.
- W2950846650 citedByCount "0" @default.
- W2950846650 crossrefType "journal-article" @default.
- W2950846650 hasAuthorship W2950846650A5001180898 @default.
- W2950846650 hasAuthorship W2950846650A5021324401 @default.
- W2950846650 hasAuthorship W2950846650A5024989470 @default.
- W2950846650 hasAuthorship W2950846650A5048198045 @default.
- W2950846650 hasAuthorship W2950846650A5057691408 @default.
- W2950846650 hasAuthorship W2950846650A5080574479 @default.
- W2950846650 hasAuthorship W2950846650A5090012953 @default.
- W2950846650 hasConcept C178790620 @default.
- W2950846650 hasConcept C185592680 @default.
- W2950846650 hasConcept C2775937945 @default.
- W2950846650 hasConcept C2776568683 @default.
- W2950846650 hasConcept C2776593056 @default.
- W2950846650 hasConcept C2778213062 @default.
- W2950846650 hasConcept C2780906977 @default.
- W2950846650 hasConcept C521977710 @default.
- W2950846650 hasConcept C55493867 @default.
- W2950846650 hasConcept C71240020 @default.
- W2950846650 hasConceptScore W2950846650C178790620 @default.
- W2950846650 hasConceptScore W2950846650C185592680 @default.
- W2950846650 hasConceptScore W2950846650C2775937945 @default.
- W2950846650 hasConceptScore W2950846650C2776568683 @default.
- W2950846650 hasConceptScore W2950846650C2776593056 @default.
- W2950846650 hasConceptScore W2950846650C2778213062 @default.
- W2950846650 hasConceptScore W2950846650C2780906977 @default.
- W2950846650 hasConceptScore W2950846650C521977710 @default.
- W2950846650 hasConceptScore W2950846650C55493867 @default.
- W2950846650 hasConceptScore W2950846650C71240020 @default.
- W2950846650 hasLocation W29508466501 @default.
- W2950846650 hasOpenAccess W2950846650 @default.
- W2950846650 hasPrimaryLocation W29508466501 @default.
- W2950846650 hasRelatedWork W1964406082 @default.
- W2950846650 hasRelatedWork W1965245116 @default.
- W2950846650 hasRelatedWork W1983191072 @default.
- W2950846650 hasRelatedWork W2023135278 @default.
- W2950846650 hasRelatedWork W2030440890 @default.
- W2950846650 hasRelatedWork W2037671541 @default.
- W2950846650 hasRelatedWork W2042763094 @default.
- W2950846650 hasRelatedWork W2063531734 @default.
- W2950846650 hasRelatedWork W2072149721 @default.
- W2950846650 hasRelatedWork W2092591126 @default.
- W2950846650 hasRelatedWork W2949658895 @default.
- W2950846650 hasRelatedWork W2950090920 @default.
- W2950846650 hasRelatedWork W2950418097 @default.
- W2950846650 hasRelatedWork W2950671000 @default.
- W2950846650 hasRelatedWork W2950786947 @default.
- W2950846650 hasRelatedWork W2951497960 @default.
- W2950846650 hasRelatedWork W2951814169 @default.
- W2950846650 hasRelatedWork W2952009309 @default.
- W2950846650 hasRelatedWork W2953050116 @default.
- W2950846650 hasRelatedWork W2977732665 @default.
- W2950846650 isParatext "false" @default.
- W2950846650 isRetracted "false" @default.
- W2950846650 magId "2950846650" @default.
- W2950846650 workType "article" @default.