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- W2950851906 abstract "The first-order rate constants for the decomposition of Na[ClO3] and Na[ClO4] when studied by X-p.e.s. are shown to have a linear dependence on the intensity of the ionising radiation used. A simple steady-state model, which emphasises the role of molecular excitons in the decomposition process, is constructed to explain this behaviour. Variable temperature studies in the range 293–113 K indicate that the rate of photo-induced decomposition of Na[ClO3] increases as the temperature is lowered, and analysis of the mode of decomposition suggests that the temperature-dependence arises from thermal deactivation of the molecular exciton, [ClO*3]–." @default.
- W2950851906 created "2019-06-27" @default.
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- W2950851906 date "1978-11-07" @default.
- W2950851906 modified "2023-09-24" @default.
- W2950851906 title "ChemInform Abstract: X-RAY PHOTOELECTRON SPECTROSCOPIC (X-P.E.S.) STUDIES ON IN SITU PHOTOINDUCED DECOMPOSITION OF INORGANIC MOLECULAR IONS. PART 2. NA(CLOX) SYSTEM- MECHANISTIC (X = 3,4) AND VARIABLE-TEMPERATURE (X = 3) INVESTIGATIONS" @default.
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- W2950851906 doi "https://doi.org/10.1002/chin.197845042" @default.
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