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- W2950863722 endingPage "864" @default.
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- W2950863722 abstract "Iodine oxidation of B3H8− in glyme solution to produce (glyme)B3H7, followed by displacement of the coordinated glyme by reaction with anhydrous ammonia provides a safe and convenient preparation of ammonia triborane, NH3B3H7 (1). X-ray crystallographic determinations and DFT computational studies of both NH3B3H7 and the NH3B3H7·18-crown-6 adduct demonstrate that while computations predict a symmetric single bridging-hydrogen conformation, NH3B3H7 has a highly asymmetric structure in the solid-state that results from intermolecular N−H+···H−−B dihydrogen bonding interactions. Studies of its hydrolytic reactions have shown that upon the addition of acid or an appropriate transition metal catalyst, aqueous solutions of 1 rapidly release hydrogen, with 6.1 materials wt % H2-release being achieved from a 22.7 wt % aqueous solution of 1 at room temperature in the presence of 5 wt % Rh/Al2O3 (1.1 mol% Rh). The rate of H2-release was controlled by both the catalyst loadings and temperature." @default.
- W2950863722 created "2019-06-27" @default.
- W2950863722 creator A5056500036 @default.
- W2950863722 creator A5073756727 @default.
- W2950863722 creator A5086747400 @default.
- W2950863722 date "2008-12-15" @default.
- W2950863722 modified "2023-10-16" @default.
- W2950863722 title "Ammonia Triborane: A New Synthesis, Structural Determinations, and Hydrolytic Hydrogen-Release Properties" @default.
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- W2950863722 doi "https://doi.org/10.1021/ja808045p" @default.
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