FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2950869426> ?p ?o ?g. }

• W2950869426 endingPage "16689" @default.
• W2950869426 startingPage "16681" @default.
• W2950869426 abstract "Self-assembly of amphiphilic molecules largely depends on the structure and electronic properties of the polar head groups. An important class of amphiphiles with technological applications comprises the discotic liquid crystal (DLC) amphiphiles. Here, we report remarkable differences in the self-assembly properties of two similar discotic amphiphiles with dissimilar polar head groups, viz., imidazole-tethered with hexaalkoxytriphenylene (neutral-ImTp) and imidazolium-tethered with hexaalkoxytriphenylene (ionic-ImTp). Surface manometry reveals that the ionic-ImTp exhibits a larger limiting area, higher collapse pressure, and smaller compressional elastic modulus at the air–water interface as compared to the neutral-ImTp system. At the air–solid interface, ionic-ImTp can be transferred only up to a bilayer structure with undulated morphology, whereas the neutral-ImTp exhibits smooth morphology and higher transfer efficiency. These results are explained by density functional theory (DFT) calculations and molecular dynamics (MD) simulations, which elucidated that the Coulombic interaction is the dominant factor that controls the organization of these molecules. DFT calculations predicted a T-shaped π-stacking geometry for the ionic-ImTp and a parallel-displaced stacking geometry for the neutral-ImTp. MD simulation predicted the orientation of molecules and their strength of hydrogen bonding. Understanding the intermolecular interactions governing self-assembly is important to engineer molecular packing that controls the charge transport in DLC-based organic electronics." @default.
• W2950869426 created "2019-06-27" @default.
• W2950869426 creator A5053997137 @default.
• W2950869426 creator A5064151051 @default.
• W2950869426 creator A5069138996 @default.
• W2950869426 creator A5085584463 @default.
• W2950869426 creator A5091163700 @default.
• W2950869426 creator A5091533240 @default.
• W2950869426 date "2019-06-14" @default.
• W2950869426 modified "2023-09-27" @default.
• W2950869426 title "Influence of Coulombic Interaction on the Interfacial Self-Assembly of Discotic Liquid Crystal Amphiphiles: A Combined Experimental and Computer Simulation Study" @default.
• W2950869426 cites W1976833368 @default.
• W2950869426 cites W1982955377 @default.
• W2950869426 cites W1990011367 @default.
• W2950869426 cites W1994365947 @default.
• W2950869426 cites W1995697647 @default.
• W2950869426 cites W1996953504 @default.
• W2950869426 cites W2000131589 @default.
• W2950869426 cites W2003949305 @default.
• W2950869426 cites W2007701663 @default.
• W2950869426 cites W2014911621 @default.
• W2950869426 cites W2023271753 @default.
• W2950869426 cites W2023723774 @default.
• W2950869426 cites W2027977370 @default.
• W2950869426 cites W2028046413 @default.
• W2950869426 cites W2029913975 @default.
• W2950869426 cites W2035687084 @default.
• W2950869426 cites W2038533471 @default.
• W2950869426 cites W2043668344 @default.
• W2950869426 cites W2057918301 @default.
• W2950869426 cites W2060079863 @default.
• W2950869426 cites W2060910958 @default.
• W2950869426 cites W2067174909 @default.
• W2950869426 cites W2068845502 @default.
• W2950869426 cites W2071969569 @default.
• W2950869426 cites W2073336514 @default.
• W2950869426 cites W2087427549 @default.
• W2950869426 cites W2128572087 @default.
• W2950869426 cites W2142145613 @default.
• W2950869426 cites W2143981217 @default.
• W2950869426 cites W2148284063 @default.
• W2950869426 cites W2163542639 @default.
• W2950869426 cites W2171268876 @default.
• W2950869426 cites W2172114355 @default.
• W2950869426 cites W2339938026 @default.
• W2950869426 cites W2589236205 @default.
• W2950869426 cites W2594042868 @default.
• W2950869426 cites W2606142660 @default.
• W2950869426 cites W2756677810 @default.
• W2950869426 cites W2811002592 @default.
• W2950869426 cites W2910893221 @default.
• W2950869426 doi "https://doi.org/10.1021/acs.jpcc.9b02713" @default.
• W2950869426 hasPublicationYear "2019" @default.
• W2950869426 type Work @default.
• W2950869426 sameAs 2950869426 @default.
• W2950869426 citedByCount "3" @default.
• W2950869426 countsByYear W29508694262021 @default.
• W2950869426 countsByYear W29508694262023 @default.
• W2950869426 crossrefType "journal-article" @default.
• W2950869426 hasAuthorship W2950869426A5053997137 @default.
• W2950869426 hasAuthorship W2950869426A5064151051 @default.
• W2950869426 hasAuthorship W2950869426A5069138996 @default.
• W2950869426 hasAuthorship W2950869426A5085584463 @default.
• W2950869426 hasAuthorship W2950869426A5091163700 @default.
• W2950869426 hasAuthorship W2950869426A5091533240 @default.
• W2950869426 hasConcept C13274807 @default.
• W2950869426 hasConcept C147597530 @default.
• W2950869426 hasConcept C154881586 @default.
• W2950869426 hasConcept C15920480 @default.
• W2950869426 hasConcept C159467904 @default.
• W2950869426 hasConcept C159985019 @default.
• W2950869426 hasConcept C161790260 @default.
• W2950869426 hasConcept C166950319 @default.
• W2950869426 hasConcept C171250308 @default.
• W2950869426 hasConcept C178790620 @default.
• W2950869426 hasConcept C185592680 @default.
• W2950869426 hasConcept C192157962 @default.
• W2950869426 hasConcept C192562407 @default.
• W2950869426 hasConcept C26856880 @default.
• W2950869426 hasConcept C32909587 @default.
• W2950869426 hasConcept C33347731 @default.
• W2950869426 hasConcept C41625074 @default.
• W2950869426 hasConcept C49040817 @default.
• W2950869426 hasConcept C521977710 @default.
• W2950869426 hasConcept C55493867 @default.
• W2950869426 hasConcept C59593255 @default.
• W2950869426 hasConcept C67407626 @default.
• W2950869426 hasConcept C8010536 @default.
• W2950869426 hasConceptScore W2950869426C13274807 @default.
• W2950869426 hasConceptScore W2950869426C147597530 @default.
• W2950869426 hasConceptScore W2950869426C154881586 @default.
• W2950869426 hasConceptScore W2950869426C15920480 @default.
• W2950869426 hasConceptScore W2950869426C159467904 @default.
• W2950869426 hasConceptScore W2950869426C159985019 @default.
• W2950869426 hasConceptScore W2950869426C161790260 @default.
• W2950869426 hasConceptScore W2950869426C166950319 @default.
• W2950869426 hasConceptScore W2950869426C171250308 @default.
• W2950869426 hasConceptScore W2950869426C178790620 @default.

• next