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- W2950871175 abstract "We have synthesized pyrite-type PtO2 (py-PtO2) at 50-60 GPa and successfully recovered it at 1 bar. The observed O-O stretching vibration in Raman spectra provides direct evidence for inter-oxygen bonding in the structure. We also identified the O-H vibrations in py-PtO2 synthesized from the low-temperature areas, indicating hydrogenation, py-PtO2H x ( x ≤ 1). Diffraction patterns are consistent with a range of degrees of hydrogenation controlled by temperature. We found that py-PtO2 has a high bulk modulus, 314 ± 4 GPa. The chemical behaviors found in py-PtO2 have implications for the hydrogen storage in materials with anion-anion bonding, and the geochemistry of oxygen, hydrogen, and transition metals in the deep planetary interiors." @default.
- W2950871175 created "2019-06-27" @default.
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- W2950871175 date "2019-07-01" @default.
- W2950871175 modified "2023-09-26" @default.
- W2950871175 title "The O-O Bonding and Hydrogen Storage in the Pyrite-type PtO2." @default.
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- W2950871175 doi "https://doi.org/10.1021/acs.inorgchem.9b00046" @default.
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