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- W2950871750 abstract "A new general method for the synthesis of pyrrole-2,5-dicarbaldehyde and its 3-mono- and 3,4-disubstituted derivatives is reported. It involves the intermediate formation of the corresponding 2,5-bis(1,3-benzodithiol-2-yl)pyrroles followed by hydrolysis with HgO–35% aq. HBF4–DMSO. Pyrrole-2,5-dicarbaldehyde was obtained in overall yields of 43–65%, whilst that of the derivatives was 32–90%. Moreover the methylation of the corresponding dithiolic intermediate with further hydrolysis resulted in the formation of 1-methylpyrrole-2,5-dicarbaldehyde in 90% overall yield." @default.
- W2950871750 created "2019-06-27" @default.
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- W2950871750 date "2010-08-19" @default.
- W2950871750 modified "2023-09-26" @default.
- W2950871750 title "ChemInform Abstract: A Convenient General Method for the Synthesis of Pyrrole-2,5- dicarbaldehydes." @default.
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- W2950871750 doi "https://doi.org/10.1002/chin.199410160" @default.
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