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- W2950872022 abstract "Study of the reaction by very-low-pressure pyrolysis (VLPP) in the temperature range of 550–850°K yields for the high-pressure Arrhenius parameters where θ = 2.303RT in kcal/mole. These in turn yield for the high-pressure second-order recombination of tBu + NO, k−1 = (3.5 ± 1.7) × 109 1./mole·sec at 600°K. For the competing reaction l./mole·sec and E4 ≥ 4.2 kcal/mole. The bond dissociation energy DHo (tBu-NO) was determined to be (39.5 ± 1.5) kcal/mole, both from the equilibrium constant and from the activation energy of reaction (1), obtained from RRKM calculations. A ‘free-volume’ model for the transition state for dissociation is consistent with the data. A limited study of the system at 8–200 torr showed an extremely rapid inhibition by products and a very complex set of products." @default.
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- W2950872022 date "1975-05-13" @default.
- W2950872022 modified "2023-09-28" @default.
- W2950872022 title "ChemInform Abstract: THE PYROLYSIS OF 2-NITROSOISOBUTANE AND THE BOND DISSOCIATION ENERGIES OF NITROSO COMPOUNDS" @default.
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- W2950872022 doi "https://doi.org/10.1002/chin.197519124" @default.
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