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- W2950872562 abstract "This review focuses on synthesis, structure and binding properties of crown compounds and their open-chain analogues containing a trithiadiazapentalene building block. This heterocyclic unit favours in particular the complexation and solvent extraction of the soft transition metal ions Ag(I), Pd(II), Hg(II) and Au(III). The redox active system trithiadiazapentalene/trithiotriuret introduced into a crown ring allows the control of Ag(I) and Hg(II) phase transfer in solvent extraction experiments. Crystal structures of metal complexes with these pentaleno crown compounds show significant differences of both SS bond lengths of the trithiadiazapentalene unit and package arrangements in the cell." @default.
- W2950872562 created "2019-06-27" @default.
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- W2950872562 date "2001-11-01" @default.
- W2950872562 modified "2023-10-03" @default.
- W2950872562 title "Macrocyclic and open-chain ligands with the redox switchable trithiadiazapentalene unit: synthesis, structures and complexation phenomena" @default.
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- W2950872562 doi "https://doi.org/10.1016/s0010-8545(01)00397-6" @default.
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