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- W2950873083 abstract "Mg 3 MnH 7 was synthesised by reacting MgH 2 with manganese powder in a 3:1 molar ratio at 20 kbar and 1070 K for 120 min, and investigated by neutron powder diffraction on its deuteride. It crystallises with the hexagonal Mg 3 ReH 7 structure type (space group P6 3 /mmc, Z=2, a=4.7099(1), c=10.2861(3) A (hydride); a=4.6998(1), c=10.2590(2) A (deuteride). Manganese is nearly octahedrally co-ordinated by deuterium with bond distances of 1.629(3) A and bond angles of 89.17(14) and 90.83(2)°. An additional deuteride-anion is co-ordinated by five magnesium cations in a trigonal pyramidal way. Mg 3 MnH 7 decomposes between 530 K and 640 K under 1 bar hydrogen pressure into elemental manganese and magnesium. Its hydrogen storage efficiency is 5.2 wt % or 118.5 g H 2 l -1 ." @default.
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- W2950873083 date "1998-01-01" @default.
- W2950873083 modified "2023-09-26" @default.
- W2950873083 title "Mg3MnH7, containing the first known hexahydridomanganese(I) complex" @default.
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