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- W2950874031 abstract "A new active Lewis acid–Lewis base bifunctional asymmetric catalyst 7 was developed using carbohydrate as a scaffold and this catalyst was applied to the asymmetric cyanosilylation of aldehydes and acetophenone. The β-Ph group at the 6-position of 7 was found to be important for a high asymmetric induction (up to 80% ee) by bringing the Al and the phosphine oxide at optimum positions for a dual activation of carbonyl compounds and TMSCN." @default.
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- W2950874031 date "2000-04-01" @default.
- W2950874031 modified "2023-10-16" @default.
- W2950874031 title "Design of a new bifunctional asymmetric catalyst from carbohydrates: application to catalytic asymmetric cyanosilylation of aldehydes and acetophenone" @default.
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- W2950874031 doi "https://doi.org/10.1016/s0040-4039(00)00174-x" @default.
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