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• W2950876503 abstract "A novel metal-free tandem Csp3-H bond functionalization of ketones and 1,3-dipolar cycloaddition has been developed. An efficient approach to a variety of oxazole and isoxazoline derivatives is demonstrated using the 1,3-dipolar cycloaddition of alkynes and alkenes to nitrile oxides generated by reactions of methyl ketones with tert-butyl nitrite. This new protocol provides access to a variety of isoxazolines with diverse functionalities. An isoxazole generated in this way was found to have significant antifungal activity." @default.
• W2950876503 created "2019-06-27" @default.
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• W2950876503 date "2019-06-13" @default.
• W2950876503 modified "2023-09-24" @default.
• W2950876503 title "Synthesis of 3-Acyl-isoxazoles and Δ²-Isoxazolines from Methyl Ketones, Alkynes or Alkenes, and <i>tert</i>-Butyl Nitrite via a Csp³–H Radical Functionalization/Cycloaddition Cascade" @default.
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• W2950876503 doi "https://doi.org/10.1021/acs.orglett.9b01683" @default.
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