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• W2950876589 abstract "Reactions of (triphenylsilyl)ethylene oxide (1) with simple Grignard reagents such as EtMgBr and PhMgBr have been reported to yield crystalline hydroxysilanes assigned as the α-hydroxy silanes expected from β opening of the epoxide. Reinvestigation of these reactions showed that the hydroxysilanes were the β-hydroxy silanes 4 and 7 expected from a rearrangement−trapping sequence; a bromohydrin, assigned as the α-bromo-β-hydroxy silane 9 from α opening, and (triphenylsilyl)acetaldehyde (8) were also formed." @default.
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• W2950876589 date "1996-01-01" @default.
• W2950876589 modified "2023-10-15" @default.
• W2950876589 title "Reactions of (Triphenylsilyl)ethylene Oxide with Grignard Reagents (and with MgBr₂). A Reinvestigation" @default.
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• W2950876589 doi "https://doi.org/10.1021/jo9604853" @default.
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