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- W2950897066 abstract "Indium-mediated reactions have gained increasing popularity over the past decade as environmentally benign tools in organic synthesis. Since the first ionization potential of indium is 5.8 eV, that is as low as those of lithium and sodium, it would be easy for indium(0) to promote SET (single electron transfer) processes. In addition, indium(0) is comparatively stable in air. Indium(III) also attracts considerable attention as water-tolerant and low-toxicity Lewis acid for the activation of C=O and C=N bonds. Herein we describe the development of indium-promoted diastereoselective allylation, radical cyclization, tandem carboindation and coupling reaction, tandem nucleophilic addition and cyclization, and tandem intramolecular nucleophilic attack/intermolecular cycloaddition/dehydration reaction." @default.
- W2950897066 created "2019-06-27" @default.
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- W2950897066 date "2009-01-01" @default.
- W2950897066 modified "2023-10-16" @default.
- W2950897066 title "Development of Synthetic Methods with Indium" @default.
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- W2950897066 doi "https://doi.org/10.5059/yukigoseikyokaishi.67.239" @default.
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