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- W2950897647 abstract "Carbonyl ruthenium(II) 5,10,15-tris(4-R-phenyl)-20-(4-hydroxyphenyl)porphyrins (R = Cl, Me) covalently attached to Merrifield's peptide resin were prepared. The catalyst with R = Cl was found to efficiently catalyze Cl2pyNO epoxidation of a wide variety of alkenes, including aromatic and aliphatic terminal alkenes, cis- and trans-stilbene, cyclohexene and cyclooctene, α,β-unsaturated ketones, conjugated enyne, glycal, and protected α-amino alkene. Unusual selectivities were observed for the epoxidations of 1,5-cyclooctadiene, cis-1-phenyl-3-penten-1-yne (9), 3,4,6-tri-O-acetyl-d-glucal (11), and 2-(Boc-amino)-1-phenylbut-3-ene (13), which feature a complete bisepoxide selectivity (1,5-cyclooctadiene), unprecedentedly high cis:trans ratio (9), and complete diastereoselectivity (11 and 13). The new heterogenized metalloporphyrin epoxidation catalysts are of high stability and reusability." @default.
- W2950897647 created "2019-06-27" @default.
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- W2950897647 creator A5071447194 @default.
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- W2950897647 date "2000-05-20" @default.
- W2950897647 modified "2023-10-16" @default.
- W2950897647 title "Polymer-Supported Ruthenium Porphyrins: Versatile and Robust Epoxidation Catalysts with Unusual Selectivity" @default.
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- W2950897647 doi "https://doi.org/10.1021/ja000461k" @default.
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