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- W2950904733 abstract "Crystals of the title compound are orthorhombic, space group Pbca, with a= 31.822(15), b= 11.047(6), c= 12.426(7)A, and Z= 8. The structure was solved using multisolution direct methods and refined by least squares to R 0.054 (R′ 0.059) for 1 964 observed diffractometer data. Phosphorus adopts a distorted tetrahedral geometry with mean Se–P–C and C–P–C angles of 113.1 and 105.6° respectively. The P–Se bond length [2.094(2)A] is the shortest reported for a tertiary phosphine selenide and is attributed to the electron-withdrawing properties of the (C6H4CF3-m) groups and the consequent increased s character of the phosphorus orbital involved in bonding with selenium." @default.
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- W2950904733 date "1984-06-05" @default.
- W2950904733 modified "2023-09-27" @default.
- W2950904733 title "ChemInform Abstract: DONOR PROPERTIES OF ARYLPHOSPHINES TOWARDS SELENIUM: X-RAY CRYSTAL STRUCTURE OF TRIS(M-TRIFLUOROMETHYLPHENYL)PHOSPHINE SELENIDE" @default.
- W2950904733 cites W2058880536 @default.
- W2950904733 doi "https://doi.org/10.1002/chin.198423079" @default.
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