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• W2950919363 abstract "The substrate-controlled RhI-catalyzed conjugate addition of aryl- and alkenylboronic acids to alpha,beta-unsaturated esters which bear gamma- and delta-oxygen substituents takes place in a highly anti diastereoselective fashion either when using gamma-hydroxyl unprotected starting materials or when the gamma-oxygen substituent is protected with a nonbulky group. The delta-oxygen substituent plays a role in the stereoselectivity of the reaction, and better results are obtained when this OH-group is protected." @default.
• W2950919363 created "2019-06-27" @default.
• W2950919363 creator A5065389021 @default.
• W2950919363 creator A5075064692 @default.
• W2950919363 date "2007-07-31" @default.
• W2950919363 modified "2023-10-18" @default.
• W2950919363 title "Stereoselective Conjugate Addition of Aryl- and Alkenylboronic Acids to Acyclic γ,δ-Oxygen-Substituted α,β-Enoates" @default.
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• W2950919363 doi "https://doi.org/10.1021/ol7016033" @default.
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