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- W2950921858 abstract "The S-methylation of N-(trimethylsilylmethyl)thioureas and the subsequent desilylation of the silylmethyl group generates N-unsubstituted azomethine ylides having both methylthio and amino groups at the ylide carbon. These azomethine ylides undergo successful cycloaddition to electron-deficient olefins, acetylenes and aldehydes. As the methylthio group is eliminated under the reaction conditions to produce the corresponding pyrrolines, pyrroles and 2-oxazolines bearing the amino group at 2-position, these azomethine ylides can be synthetic equivalents of nonstabilized aminonitrile ylides that are otherwise relatively inaccessible." @default.
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- W2950921858 date "2000-09-01" @default.
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- W2950921858 title "Cycloaddition of New N -Unsubstituted Azomethine Ylides Generated from N -(Trimethylsilylmethyl)thioureas to Electron-Deficient Olefins, Acetylenes and Aldehydes, Synthetic Equivalents of Nonstabilized Aminonitrile Ylides 1" @default.
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- W2950921858 doi "https://doi.org/10.1016/s0040-4020(00)00688-8" @default.
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