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- W2950925355 abstract "Heterometallic copper(II)-lanthanide(III) complexes have been made with a variety of exclusively O-donor ligands including betaines (zwitterionic carboxylates) and chloroacetate, which are dinuclear CuLn, tetranuclear Cu2Ln2, pentanuclear Cu3Ln2, and octadecanuclear Cu12 complexes. The results show that subtle changes in both the carboxylates and acidity of the reaction solution can cause drastic changes in the structures of the products. Magnetic studies exhibit that shielding of the Ln3+ 4f electrons by the outer shell electrons is very effective to preclude significant coupling interaction between the Ln3+ 4f electrons and Cu2+ 3d electrons in either a mono-atomic hydroxide-bridged, or a carboxylate-bridged system." @default.
- W2950925355 created "2019-06-27" @default.
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- W2950925355 date "2010-08-27" @default.
- W2950925355 modified "2023-09-25" @default.
- W2950925355 title "Synthesis, structures and magnetic properties of a series of polynuclear copper(II)-lanthanide( III) complexes assembled with carboxylate and hydroxide ligands" @default.
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- W2950925355 doi "https://doi.org/10.1002/cjoc.20000180503" @default.
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