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- W2950943379 abstract "Depending on the reaction conditions either 2,6-disubstituted 2,3,5,6-tetrahydro-4H-1,3-thiazin-4-ones 4 or 1,6-disubstituted 2-thiouracils 5 are readily prepared by base-catalyzed cyclization of N-propenoylthioureas 3. Compounds 5 could also be obtained by Dimroth-type rearrangement of 1,3-thiazin-4-ones 4 under the same reaction conditions.Eine einfache Synthese von substituierten Perhydro-1,3-thiazin-4-onen und 2-Thioxoperhydro-4-pyrimidinonenDie basisch katalysierte Cyclisierung der N-Propenoylthioharnstoffe 3 liefert je nach den Reaktionsbedingungen entweder 2,6-disubstituierte 2,3,5,6-Tetrahydro-4H-1,3-thiazin-4-one 4 oder 1,6-disubstituierte 2-Thiouracile 5. Unter denselben Reaktionsbedingungen konnen die Verbindungen 5 durch eine Art Dimroth-Umlagerung aus den 1,3-Thiazin-4-onen 4 erhalten werden." @default.
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- W2950943379 date "1989-01-10" @default.
- W2950943379 modified "2023-09-23" @default.
- W2950943379 title "ChemInform Abstract: A Facile Synthesis of Substituted Perhydro-1,3-thiazin-4-ones and 2-Thioxoperhydro-4-pyrimidinones." @default.
- W2950943379 cites W1982419654 @default.
- W2950943379 doi "https://doi.org/10.1002/chin.198902083" @default.
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