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- W2950951192 abstract "Abstract Ketones and esters ( 4 ) were effectively prepared by reaction of Grignard reagents with acyl tributylphosphonium chlorides ( 2 ), diethyl acylphosphonates ( 5 ), or diisopropyl acylphosphonate ( 6 ) derived from acid chlorides and chloroformates ( 1 ). Although by the method with 2 , 4 is prepared in one-pot operation from 1 and generally in a higher yield, the method with 5 or 6 proved to compensate for the synthesis of 4 with 2 in some respects. The reactivities of 2 , 5 , and 6 as electrophiles were also evaluated by comparing their reduction potentials with those of acid chlorides." @default.
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- W2950951192 date "2010-06-17" @default.
- W2950951192 modified "2023-09-24" @default.
- W2950951192 title "ChemInform Abstract: Reactions of Acyl Tributylphosphonium Chlorides and Dialkyl Acylphosphonates with Grignard and Organolithium Reagents." @default.
- W2950951192 cites W2011140404 @default.
- W2950951192 doi "https://doi.org/10.1002/chin.199904086" @default.
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