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- W2950952493 abstract "Dynamic kinetic resolution by highly stereoselective carbon-carbon bond formation utilizing 2-oxoimidazolidine-4-carboxylate as a chiral auxiliary was exploited. The reaction of tert-butyl(4S)-1-methyl-3-(2-bromopropionyl)-2-oxoimidazolidine-4-carboxylate (1) with sodium dimethyl malonate in HMPA at room temperature predominantly afforded tert-butyl(4S)-1-methyl-3-((2R)-2-methyl-3,3-bis(methoxycarbonyl)propionyl)-2-oxoimidazolidine-4-carboxylate ((S,R)-2a) in a good yield." @default.
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- W2950952493 date "2010-08-16" @default.
- W2950952493 modified "2023-10-08" @default.
- W2950952493 title "ChemInform Abstract: Dynamic Kinetic Resolution Utilizing a Chiral Auxiliary by Stereoselective SN2 Alkylation with Malonic Ester Enolate." @default.
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- W2950952493 doi "https://doi.org/10.1002/chin.199550006" @default.
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