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- W2950956680 abstract "Abstract Two new ligands, N,N-bis(3,5-dimethylpyrazol-1-ylmethyl)benzylamine (bpmba) and N,N,N′,N′- tetrakis(3,5-dimethylpyrazol-1-ylmethyl)-α,α′-di- amino-m-xylene (bpmdx) have been synthesized. Using these ligands, copper(II) complexes of the type [Cu(bpmba)(Cl)2](Cl)2, [Cu2 (bpmba)2(OCH3)2]- (BF4)2 and [Cu2(bpmdx)(X)2]Y2 where X = OCH3 or Cl and Y = Cl or BF4 have been prepared and characterized on the basis of elemental analysis, fast atom bombardment mass spectrometry, and UV—Vis spectroscopy. These show the ligands to coordinate as an N3 and an N6 donor set respectively. The ability of the complexes to catalyze the oxidation of catechol to quinone was studied by following the appearance of quinone spectrophotometrically. The binuclear complex [Cu2(bpmdx)(OCH3)2]- (BF4)2 reacts fastest with an oxidase activity of 0.467 μmol/mg min while the other three complexes have slower rates of oxidation." @default.
- W2950956680 created "2019-06-27" @default.
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- W2950956680 date "1989-12-19" @default.
- W2950956680 modified "2023-09-25" @default.
- W2950956680 title "ChemInform Abstract: Novel Mono- and Binuclear Cu(II) Complexes: Synthesis, Characterization and Catecholase Activity." @default.
- W2950956680 cites W2036591933 @default.
- W2950956680 doi "https://doi.org/10.1002/chin.198951254" @default.
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