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- W2950957515 abstract "Abstract Ternary pnictides MNi4X2 (M ≡ Zr, Hf; X ≡ As, P) and the corresponding rare earth arsenides LnNi4As2 (Ln = Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Y) have been synthesized from their elements. They all have isotypic tetragonal crystal structures, space group P42/mnm with two formulae per unit cell. The X-ray structure, performed on single crystals of ZrNi4P2 (R = 0.028, 122 independent reflections) exhibits tetrahedral Ni4 clusters in a marcasite-type host structure. The Ni4 clusters with common edges develop as infinite linear chains along the ¦011¦ direction. While most of the compounds of marcasite-type are semiconducting, first electrical measurements reveal a metallic conduction. Preliminary magnetic measurements on rare-earth compounds indicate a Curie-Weiss paramagnetism without magnetic ordering above 4 K." @default.
- W2950957515 created "2019-06-27" @default.
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- W2950957515 date "1989-11-21" @default.
- W2950957515 modified "2023-09-26" @default.
- W2950957515 title "ChemInform Abstract: Tetrahedral Ni4 Clusters in a Marcasite-Type Host Structure: The Preparation and Crystal Structure of MNi4X2 Compounds (X: P, As; M: Zr, Hf, Y, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu)." @default.
- W2950957515 cites W2040444875 @default.
- W2950957515 doi "https://doi.org/10.1002/chin.198947002" @default.
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