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- W2950961520 abstract "An average structure of incommensurately modulated monoclinic InTi0.75Fe0.25O3.375 was determined using single-crystal X-ray diffraction. Unit cell parameters are a = 5.9207(8), b = 3.4249(5), c = 6.3836(9), and β = 107.96(1) with Z = 2, and the space group is C2/m. The structure with pseudorhombohedral symmetry involves two metal positions: M1, practically occupied by In, and M2, by Ti and Fe. Two layers are alternately stacked along the c axis; one is an edge-shared M1O6 octahedral sheet and another consists of bipyramidal coordination at M2 sites. In the bipyramidal layer, a honeycomb lattice 68% occupied by oxygen ions surrounds the M2 site. These oxygen ions are subsequently displaced from their original positions to reduce mutual repulsion. This explains large displacement parameters U11 and U22 despite the normal U33 at the M2 site as well as at the oxygen site. Solid solution for the present phase is limited to InFeO3:In2Ti2O7 = 2:3 at 1300 °C according to a phase relations study in the pseudobinary system InFeO3−In2Ti2O7. We propose a hypothetical compound with an unusual ABO3 structure based on a comparison of this compound and related structures." @default.
- W2950961520 created "2019-06-27" @default.
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- W2950961520 date "2000-07-11" @default.
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- W2950961520 title "Crystal Structure of InTi<sub>0.75</sub>Fe<sub>0.25</sub>O<sub>3.375</sub> and Phase Relations in the Pseudobinary System InFeO<sub>3</sub>−In<sub>2</sub>Ti<sub>2</sub>O<sub>7</sub> at 1300 °C" @default.
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- W2950961520 doi "https://doi.org/10.1021/cm000189d" @default.
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