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- W2950963012 abstract "The synthesis of the Mn(II) phase 4H-Ba(0.5)Sr(0.5)MnO(2+delta) via the topotactic reduction of 4H-Ba(0.5)Sr(0.5)MnO(3-x) with the novel reducing agent LiH, is described. Neutron powder diffraction data show that oxide ions are deintercalated from the host structure in a disordered manner to yield tetrahedral MnO(4) coordination sites. Magnetic susceptibility and neutron powder diffraction data show that the title phase adopts a canted antiferromagnetically ordered state below T(N) = 355K, consistent with the strong magnetic coupling expected between d(5) centers." @default.
- W2950963012 created "2019-06-27" @default.
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- W2950963012 date "2008-10-29" @default.
- W2950963012 modified "2023-09-23" @default.
- W2950963012 title "Room Temperature Antiferromagnetic Order in the Mn(II) Oxide 4H-Ba<sub>0.5</sub>Sr<sub>0.5</sub>MnO<sub>2+δ</sub>" @default.
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- W2950963012 doi "https://doi.org/10.1021/ic801185z" @default.
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