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- W2950971521 abstract "The crystal structures of the dipotassium tetramethylbenzene-1,2- (1b), -1,3- (2b) and -1,4-disulfonate (4b) have been determined. The overcrowding of the six substituents in the three isomers is reflected in the puckering of the benzene rings (the degree of which increases in the order 2b < 4b < 1b) and, to some extent, in the somewhat greater lengths of the CCH3 and CS bonds (as compared to those in dipotassium 2,4,6-trimethylbenzene-1,3-disulfonate (3b), a compound which allows a larger bond-angle deformation of the benzene ring).A comparison of the observed 1H and 13C NMR data of 1b–4b with those calculated on the basis of additivity of the substituent chemical shifts (SCS's) of the methyl and sulfonate groups failed to reveal any specific information concerning the (degree and type of local) overcrowding of the polymethylbenzenedisulfonates." @default.
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- W2950971521 date "1987-10-06" @default.
- W2950971521 modified "2023-09-27" @default.
- W2950971521 title "ChemInform Abstract: The Structure of Some Overcrowded Potassium Polymethylbenzenesulfonates" @default.
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- W2950971521 doi "https://doi.org/10.1002/chin.198740050" @default.
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