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- W2950973062 abstract "Abstract The molecular structure of [Os 6 (CO) 18 PCl] is presented. The phosphorus atom is interstitially sited within a distorted trigonal prismatic array of osmium atoms. The chlorine atom bridges one edge of a triangular face of the Os 6 cage. A comparison is made between the structures Of [Os 6 (CO) 18 PCl] and its parent compound, [OS 6 (CO) 18 P] − . By using the model compounds [Ru 6 (CO) 18 P] − and Ru 6 (CO) 18 PCl, the Fenske-Hall quantum chemical technique is used to investigate the mode of bonding of the phosphorus atom in [Os 6 (CO) 18 P] − . In Ru 6 (CO) 18 PCl, the interaction of the tangential orbital of the chlorine atom with the ruthenium-ruthenium antibonding LUMO of [Ru 6 (CO) 18 P] − is the primary interfragment interaction; this results in Ru 6 (CO) 18 PCl, and by analogy [Os 6 (CO) 18 PCl], being a 92 electron cluster in contrast to [Os 6 (CO) 18 P] − which is a 90 electron cluster." @default.
- W2950973062 created "2019-06-27" @default.
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- W2950973062 date "1989-02-07" @default.
- W2950973062 modified "2023-09-26" @default.
- W2950973062 title "ChemInform Abstract: An X-Ray Crystal and Electronic Structural Investigation of the Interstitial Phosphide Cluster (Os6(CO)18PCl)" @default.
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- W2950973062 doi "https://doi.org/10.1002/chin.198906277" @default.
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