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- W2950973944 abstract "The introduction of hexavacant Dawson-type precursor K(12)[H(2)P(2)W(12)O(48)] x 24 H(2)O into a HOAc/NaOAc (OAc(-) = acetate) buffer system containing (NH(4))(2)[Ce(IV)(NO(3))(6)] and Mn(II)(OAc)(2) x 4 H(2)O led to the isolation of a new compound, Na(20)[Ce(IV)(3)Mn(IV)(2)O(6)(OAc)(6)(H(2)O)(9)](2)[Mn(III)(2)P(2)W(16)O(60)](3) x 21 H(2)O (1). Compound 1 contains unusual triple-Dawson-type polyoxoanions [Mn(III)(2)P(2)W(16)O(60)](3)(24-) and bipyramid-like 3d-4f heterometallic clusters [Ce(IV)(3)Mn(IV)(2)O(6)(OAc)(6)(H(2)O)(9)](2+), which are arranged in a 3-D supramolecular assembly with 1-D channels. The Na(+) cations and solvent water molecules reside in the channels. Crystal data for 1 are as follows: hexagonal, P6(3)/mcm (No. 193), a = 24.959(4) A, c = 26.923(5) A, gamma = 120 degrees, V = 14525(4) A(3), and Z = 2. The electrochemical and electrocatalytic properties of compound 1 have been investigated." @default.
- W2950973944 created "2019-06-27" @default.
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- W2950973944 date "2009-09-22" @default.
- W2950973944 modified "2023-09-23" @default.
- W2950973944 title "ChemInform Abstract: A New Supramolecular Assembly Based on Triple-Dawson-Type Polyoxometalate and 3d-4f Heterometallic Cluster." @default.
- W2950973944 cites W2030635418 @default.
- W2950973944 doi "https://doi.org/10.1002/chin.200938029" @default.
- W2950973944 hasPublicationYear "2009" @default.
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