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- W2950975823 abstract "The disproportionation/combination ratio in the reaction between two 3,5-di-tert-butylcumyl radicals, generated by thermolysis of the corresponding diazene, is 0.21 ± 0.03 at 60 °C in benzene. This is much larger than the value of 0.06 found for the unsubstituted cumyl radicals. It is suggested that the tert-butyl groups hinder the formation of a parallel association complex, which has been proposed to account for the much smaller amount of disproportionation in the reaction between benzylic radicals as compared with alkyl radicals." @default.
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- W2950975823 date "1988-08-30" @default.
- W2950975823 modified "2023-09-26" @default.
- W2950975823 title "ChemInform Abstract: Remote Steric Effects on the Disproportionation/Recombination Ratio of Cumyl Radicals." @default.
- W2950975823 cites W2118517483 @default.
- W2950975823 doi "https://doi.org/10.1002/chin.198835100" @default.
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