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- W2950978895 abstract "Abstract A convergent total synthesis of pironetin1 and related compound2 using a chiral building block,(1S,5S,6R)-5-hydroxybicyclo[4.1.0]heptan-2-one5 is described. Both the dithiane47 and the epoxide32 with proper substituents were employed as coupling partners to construct the whole carbon skeleton48, which was converted to (−)-pironetin1 and (−)-2 in few steps. The usefulness of5 for polyketide synthesis was demonstrated. Download : Download full-size image" @default.
- W2950978895 created "2019-06-27" @default.
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- W2950978895 date "2010-06-12" @default.
- W2950978895 modified "2023-10-03" @default.
- W2950978895 title "ChemInform Abstract: An Efficient Synthesis of Pironetins Employing a Useful Chiral Building Block, (1S,5S,6R)-5-Hydroxybicyclo[4.1.0]heptan-2-one." @default.
- W2950978895 cites W2108143044 @default.
- W2950978895 doi "https://doi.org/10.1002/chin.199946231" @default.
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